https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:21302 Wed 11 Apr 2018 15:52:08 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:39790 d) ranged from 5 to 229 mL/g (median: 28 mL/g), with 63% of the Fijian soils and 35% of the Australian soils showing K_d values that exceeded the observed median Kd. Multiple linear regression showed that TOC, amorphous aluminum and iron oxides contents, anion exchange capacity, pH, and silt content, jointly explained about 53% of the variance in PFOS K_d in soils. Variable charge soils with net positive surface charges, and moderate to elevated TOC content, generally displayed enhanced PFOS sorption than in temperate or tropical soils with TOC as the only sorbent phase, especially at acidic pH ranges. For the first time, two artificial neural networks were developed to predict the measured PFOS K_d (R² = 0.80) in the soils. Overall, both TOC and surface charge characteristics of soils are important for describing PFOS sorption.]]> Thu 23 Jun 2022 14:06:17 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:33207 o), Fe(III) oxide and cow manure increased Cr(VI) retention. The effect of S^o on Cr(VI) sorption is mediated through a decrease in soil pH, which facilitated an increased retention of Cr(VI) as measured by Freundlich sorption coefficient from 0.079 (in pristine soil, pH7.15) to 21.06L/kg (in S^o amended soil, pH4.08). Also, Fe(III) oxide addition at 5% has favoured for an increase in the retention of Cr(VI) (K_f =91.15L/kg). Cow manure promoted Cr(VI) reduction, possibly due to the presence of functional groups that are present along with dissolved organic carbon and also by increased microbial activity. It is concluded that the mitigation of Cr toxicity is brought about by the addition of amendments which manipulate the properties of soil to increase retention of Cr(III) and Cr(VI).]]> Thu 21 Oct 2021 12:51:17 AEDT ]]>